Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes
نویسندگان
چکیده
منابع مشابه
Recent advances in transition-metal-catalyzed intermolecular carbomagnesiation and carbozincation
Carbomagnesiation and carbozincation reactions are efficient and direct routes to prepare complex and stereodefined organomagnesium and organozinc reagents. However, carbon-carbon unsaturated bonds are generally unreactive toward organomagnesium and organozinc reagents. Thus, transition metals were employed to accomplish the carbometalation involving wide varieties of substrates and reagents. R...
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The first addition of alcohols to carbodiimides catalyzed by transition-metal-free compounds employs 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and its alkali metal salts. Isoureas are obtained in short reaction times and high yields when TBDK is used as the catalyst. Control of the coordination sphere of potassium with exogenous chelating ligands, in combination with mechanistic DFT calculation...
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ژورنال
عنوان ژورنال: Comments on Inorganic Chemistry
سال: 2016
ISSN: 0260-3594,1548-9574
DOI: 10.1080/02603594.2016.1183487